Thiourea (TU) adsorbed at Ag electrodes both in neutral and acidic solutions has been studied using surface enhanced Raman (SER) spectroscopy and differential capacitance measurements. The coadsorption of TU with anions may be through the NH, group in neutral solutions, and the NH: group in acidic s
In situ raman studies of polypyrrole formation on a silver electrode
β Scribed by J. Bukowska; K. Jackowska
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 245 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Raman spectroscopic evidence is given for the formation of polypyrrole on some silver electrode surfaces. Oxidation of pyrrole and its subsequent polymerisation is merely promoted by the electrode surface illuminated by daylight during oxidation-reduction cycle. For the silver electrode roughened under neonlight conditions SERS spectrum of adsorbed pyrrole molecules was only observed.
π SIMILAR VOLUMES
The preparation in situ of a silver-silver chloride reference electrode includes anodic-cathodic pretreatment of a silver electrode in a phosphate buffer solution comprising 0.1 M sodium chloride. At pH 7.0 and 25Β°C and with optimally pretreated electrodes, the potential of the Ag/AgCl electrode was
## Abstract At various potentials, the __in situ__ confocal Raman technique was employed to detect SERS signals from a silver electrode surface modified with NAD^+^ through a selfβassembled monolayer (SAM) method. The SERS bands of the NAD^+^ molecule are much more sensitive to changes in the appli