In Situ Raman Spectroelectrochemistry of Electron Transfer between Glassy Carbon and a Chemisorbed Nitroazobenzene Monolayer

First direct interfacial electron transf

First direct interfacial electron transfer between a biomolecule and a solid electrode in non-aqueous media: Direct electrochemistry of microperoxidase-11 at glassy carbon in dimethyl sulfoxide solution

✍ Patricia Ann Mabrouk 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 597 KB

The direct heterogeneous electron transfer between the imidazole complex of microperoxidase-11 (im-MP-11) and naked glassy carbon electrodes in dimethyl sulfoxide (l-3.6% H,O) containing 0.1 M tetra-n-butylammonium perchlorate has been accomplished using cyclic voltammetry. Homogeneous solutions of