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In situ opening of epoxy alcohols: a convenient alternative to the isolation of unstable epoxy alcohols

✍ Scribed by Ko, Soo Y.; Sharpless, K. Barry

Book ID
115545113
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
477 KB
Volume
51
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Enantioselective lipase-catalysed hydrol
Enantioselective lipase-catalysed hydrolysis of esters of epoxy secondary alcohols: An alternative to Sharpless oxidation
✍ Brian A Marples; Mark Rogers-Evans πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 211 KB

The enantioselectivity and yield of lipase-catalysed hydrolyses of epoxy butanoates (4) depends on R. Sharpless oxidation of the secondary allylic alcohol (8,R2=Pr) established that in the lipase-catalysed hydrolysis of (4,R2=Pr) the threo-isomer gave higher ee than the erythroisomer.