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In Situ Generation of Functionality in a Reactive Haloalkane-Based Ligand for the Design of New Porous Coordination Polymers

โœ Scribed by Kanoo, Prakash; Matsuda, Ryotaro; Sato, Hiroshi; Li, Liangchun; Jeon, Hyung Joon; Kitagawa, Susumu


Book ID
121015772
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
253 KB
Volume
52
Category
Article
ISSN
0020-1669

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An essential process in nitrogen fixation is cleavage of molecular nitrogen. [1] Several studies using model systems have confirmed that metal nitrides can be formed from coordinated dinitrogen providing that at least six electrons are available to formally reduce the N 2 unit to two N 3ร€ ligands. [