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Improved total synthesis of incednam

โœ Scribed by Takada, Akira; Uda, Kanjiro; Ohtani, Takashi; Tsukamoto, Shinya; Takahashi, Daisuke; Toshima, Kazunobu

Book ID
120448205
Publisher
Nature Publishing Group
Year
2013
Tongue
English
Weight
832 KB
Volume
66
Category
Article
ISSN
0021-8820

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The chiral 1,2,3,4-tetrahydroisoquinoline intermediates in the the key raw material in the Beyerman route, 3,5-dibenzyloxy-4-methoxyphenylacetic acid (1), starting from gallic acid methyl Rice and Beyerman routes to morphine, (+)-(R)-1-(3-hydroxy-4methoxybenzyl)-6-methoxy-1,2,3,4-tetrahydroisoquinol