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Improved Synthesis of the A−G Ring Segment of Brevetoxin B

✍ Scribed by Kadota, Isao; Nishii, Hiroki; Ishioka, Hiroki; Takamura, Hiroyoshi; Yamamoto, Yoshinori

Book ID
126778244
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
140 KB
Volume
71
Category
Article
ISSN
0022-3263

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✍ Hiroko Matsukura; Nobuyuki Hori; Goh Matsuo; Tadashi Nakata 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 96 KB

The IJK-ring system of brevetoxin-B was stereoselectively synthesized based on the 6-endo-cyclizations of a hydroxy methylepoxide and a hydroxy styrylepoxide, and the direct introduction of the C-4 unit as the side chain.