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Synthetic studies on brevetoxin-B. Part 1: Stereoselective synthesis of the ABC-ring system

✍ Scribed by Goh Matsuo; Hiroko Matsukura; Nobuyuki Hori; Tadashi Nakata

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
107 KB
Volume
41
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Synthetic Studies o
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A new method for constructing the ABCE ring system of azadirachtin in a stereoselective manner was developed. The synthesis of the model compound features (1) stereoselective construction of the highly hindered C8 quaternary center by an intermolecular addition reaction of an allylborane with an ald