Improved syntheses of M[Fe2(CO)8]2 (M = Si, Ge or Sn) and the X-ray crystal structure of Si[Fe2(CO)8]2
β Scribed by Skelte G. Anema; Glen C. Barris; Kenneth M. Mackay; Brian K. Nicholson
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 629 KB
- Volume
- 350
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120Β°C to afford
New 1D complexes are obtained from the reaction of 1,1Πbiphenyl-2,2Π-dicarboxylic acid (diphenic acid) with KOH and [ under hydrothermal conditions. Compounds 1 and 2 are isostructural and their structure consists of stacked helical chains of octahedral metal(II) ions. Magnetic measurements show th