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Improved Julia—Kocienski Conditions for the Methylenation of Aldehydes and Ketones.

✍ Scribed by Christophe Aissa

Publisher
John Wiley and Sons
Year
2006
Weight
39 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Improved Protocol for the Three-Component Biginelli Reactions and Biginelli-Like Mannich Reactions of Carbamates, Aldehydes, and Ketones
✍ Li-Wen Xu; Zong-Ting Wang; Chun-Gu Xia; Lyi Li; Pei-Qing Zhao 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 German ⚖ 92 KB

## Abstract A mild, convenient, and improved method for the direct three‐component __Biginelli__ and __Biginelli__‐like __Mannich__‐type reactions of carbonyl compounds in the presence of inexpensive FeCl~3~⋅6 H~2~O and Me~3~SiCl as catalysts is described. Reactions performed with carbamates can be