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Improved Control in Nitroxide-Mediated Radical Polymerization Using Supercritical Carbon Dioxide †

✍ Scribed by Aldabbagh, Fawaz; Zetterlund, Per B.; Okubo, Masayoshi


Book ID
126300362
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
281 KB
Volume
41
Category
Article
ISSN
0024-9297

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📜 SIMILAR VOLUMES


Nitroxide-Mediated Radical Precipitation
✍ Ronan McHale; Fawaz Aldabbagh; Per B. Zetterlund; Masayoshi Okubo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 247 KB

## Abstract Nitroxide‐mediated controlled/living radical precipitation polymerization of styrene in supercritical carbon dioxide has been performed using SG1 and AIBN as mediator and initiator, respectively. The equivalent bulk polymerization proceeded at a rate ≈1.58 times faster than the precipit