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Nitroxide-Mediated Radical Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide Using a Poly(dimethylsiloxane- b -methyl methacrylate) Stabilizer †

✍ Scribed by McHale, Ronan; Aldabbagh, Fawaz; Zetterlund, Per B.; Minami, Hideto; Okubo, Masayoshi

Book ID
126307155
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
228 KB
Volume
39
Category
Article
ISSN
0024-9297

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Nitroxide-Mediated Radical Dispersion Po
Nitroxide-Mediated Radical Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide Using a Poly(dimethylsiloxane-block-styrene) Alkoxyamine as Initiator and Stabilizer
✍ Ronan McHale; Fawaz Aldabbagh; Per B. Zetterlund; Masayoshi Okubo 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 188 KB

## Abstract **Summary:** Nitroxide‐mediated dispersion polymerization of styrene in supercritical carbon dioxide has been performed successfully at 110 °C using a new polymeric so‐called inistab species, which fulfils the dual functions of an initiator and a colloidal stabilizer. The inistab specie

Nitroxide-Mediated Radical Precipitation
Nitroxide-Mediated Radical Precipitation Polymerization of Styrene in Supercritical Carbon Dioxide
✍ Ronan McHale; Fawaz Aldabbagh; Per B. Zetterlund; Masayoshi Okubo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 247 KB

## Abstract Nitroxide‐mediated controlled/living radical precipitation polymerization of styrene in supercritical carbon dioxide has been performed using SG1 and AIBN as mediator and initiator, respectively. The equivalent bulk polymerization proceeded at a rate ≈1.58 times faster than the precipit