Enantiopure sulfinimine (S)-4 was employed in a Darzens-type synthesis of aziridine 2-phosphonates (-)-7/(+)-8 which were transformed into a-amino phosphonates (S)-11/(R)-12 and the first enantiopure examples of azirinyl phosphonates 13-15.
β¦ LIBER β¦
Improved Asymmetric Synthesis of Aziridine 2-Phosphonates Using ( S )-(+)-2,4,6-Trimethylphenylsulfinamide
β Scribed by Davis, Franklin A.; Ramachandar, Tokala; Wu, Yongzhong
- Book ID
- 120318965
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 174 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
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