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Immobilization of a BINOLate—Titanium Catalyst by Use of Aggregation Phenomenon.

✍ Scribed by Toshiro Harada; Masashi Nakatsugawa

Publisher
John Wiley and Sons
Year
2006
Weight
17 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Room temperature and highly enantioselective additions of alkyltitanium reagents to aldehydes catalyzed by a titanium catalyst of (R)-h8-binol
✍ Qinghan Li; Han-Mou Gau 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 482 KB 👁 2 views

## Abstract  Three alkyltitanium reagents of RTi(O‐__i__‐Pr)~3~ (R = Cy (**1a**), __i__‐Bu (**1b**), and __n__‐Bu (**1c**)) were prepared in good yields. The high‐resolution mass spectroscopy showed that **1b** and 1**c** in the gas phase are monomeric species. However, the solid state of **1a** re