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Highly Enantioselective Aryl Additions of [AlAr3(thf)] to Ketones Catalyzed by a Titanium(IV) Catalyst of (S)-Binol.

✍ Scribed by Chien-An Chen; Kuo-Hui Wu; Han-Mou Gau

Publisher
John Wiley and Sons
Year
2007
Weight
36 KB
Volume
38
Category
Article
ISSN
0931-7597

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Room temperature and highly enantioselec
Room temperature and highly enantioselective additions of alkyltitanium reagents to aldehydes catalyzed by a titanium catalyst of (R)-h8-binol
✍ Qinghan Li; Han-Mou Gau πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 482 KB πŸ‘ 1 views

## Abstract  Three alkyltitanium reagents of RTi(O‐__i__‐Pr)~3~ (R = Cy (**1a**), __i__‐Bu (**1b**), and __n__‐Bu (**1c**)) were prepared in good yields. The high‐resolution mass spectroscopy showed that **1b** and 1**c** in the gas phase are monomeric species. However, the solid state of **1a** re