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Immobilization, Characterization, and Preliminary Reactivity Studies of Halfsandwich Ruthenium Complexes on Silica

✍ Scribed by Christina M. Standfest-Hauser; Thomas Lummerstorfer; Roland Schmid; Karl Kirchner; Helmuth Hoffmann; Michael Puchberger

Book ID
106213273
Publisher
Springer Vienna
Year
2003
Tongue
English
Weight
294 KB
Volume
134
Category
Article
ISSN
0026-9247

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✍ Dharmesh Kumar; Christopher C. Landry πŸ“‚ Article πŸ“… 2007 πŸ› Elsevier Science 🌐 English βš– 434 KB

This paper presents studies on the immobilization of the polyoxometalate [PV 2 Mo 10 O 40 ] Γ€5 (referred to as ''POM'') on modified mesoporous MCM-41. The MCM-41 host material was made cationic by functionalization of the surface with [(MeO) 3 -Si(CH 2 ) 3 N + (CH 3 ) 3 ]Cl. In polar solvents, POM i