Helm, H. Nath, unpublished results. [7] X-ray structure analysis of 3a: C22H26BCI,NTi.0.5CH2C12, M=547.5; single crystal 0.22 x 0.30 x 0.30 mm'; monoclinic, P2,/n, a = 10.672(4), b = 12.079(3), ~=21.179(3) A, b= 101.93(3)", V=2671 A' , Z = 4 , pLIClrd=1.36 g cm-'. p(MoKa)=8.33 cm-', 28=2-50" in h k
Iminoethenethiones, RN:C:C:S: Characterization by Neutralization-Reionization Mass Spectrometry and G2(MP2) Theory
β Scribed by Flammang, Robert; Landu, Dinzeyi; Laurent, Sophie; Barbieux-Flammang, Monique; Kappe, C. Oliver; Wong, Ming Wah; Wentrup, Curt
- Book ID
- 126951857
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 993 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
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Neutralization of a beam of vinylidene anions, [ CH,-C] -., by xenon gives rise to a stable CIHz species, having a lifetime 2 0.4 us. Re-ionization with oxygen generates a species which is identified byits collisional activation mass spectrum as the vinylidene radical cation, [CH+Z] +..
Experiments are reported on the successful gas-phase generation of butatrienylidene H,C-CC-C: using the technique of neutralization-reionization mass spectrometry.