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Iminium ion-mediated cyclizations of 4-aryl-1,4-dihydropyridines. Regio- and stereoselective intermolecular cycloaddition reactions

โœ Scribed by Hartman, George D.; Phillips, Brian T.; Halczenko, Wasyl; Pitzenberger, Steven M.


Book ID
127238976
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
518 KB
Volume
54
Category
Article
ISSN
0022-3263

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Directed Intermolecular (4 + 2) Cycloaddition of Unactivated 1,3-Diene Substrates with High Regio-and Stereoselectivities. -Pd(0)-catalyzed cycloaddition of vinylallenes with ordinary 1,3-dienes leads to cyclohexene derivatives. High regio-and stereoselectivities are achieved under mild conditions