Imine Hydrogenation by Tribenzylphosphine Rhodium and Iridium Complexes
✍ Scribed by Landaeta, Vanessa R.; Muñoz, Bianca K.; Peruzzini, Maurizio; Herrera, Verónica; Bianchini, Claudio; Sánchez-Delgado, Roberto A.
- Book ID
- 117997820
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 128 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
## Abstract Treatment of [Ir~2~(μ‐H)(μ‐Pz)~2~H~3~(NCMe)(P__i__Pr~3~)~2~] (1) with one equivalent of HBF~4~ or [PhNHCHPh]BF~4~ affords efficient catalysts for the homogeneous hydrogenation of __N__‐benzylideneaniline. The reaction of 1 with HBF~4~ leads to the trihydride–dihydrogen complex [Ir~2~(μ
The bulky β-diiminate ligands [(2,6-C 6 H 3 X 2 )NC(Me)CHC(-Me)N(2,6-C 6 H 3 X 2 )] -(X = Me, L Me ; X = Cl, L Cl ) have been found to be effective in stabilizing low coordination numbers (CN) in Rh and Ir complexes. The 14-e complex L Me Rh(COE) (COE = cyclooctene) has a three-coordinate T-shaped R