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Imidoyl Radicals as Synthons of Unstable Acyl Radicals.

โœ Scribed by Shin-ichi Fujiwara; Takahiro Matsuya; Hajime Maeda; Tsutomu Shin-ike; Nobuaki Kambe; Noboro Sonoda

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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The previously reported tandem cyclisation of N-aryl ฮฑ-(2cyanophenyl)sulfanyl imidoyl radicals affords one quinoxaline derivative arising from exclusive 1,6-cyclisation of the final iminyl radical onto the N-aryl ring. When the imidoyl radicals are generated by addition of photolytically generated (