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Identification of high energy lines in the K-LL auger spectrum of N2

✍ Scribed by Thomas A. Carlson; W.E. Moddeman; B.P. Pullen; Manfred O. Krause

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 265 KB
Volume: 5
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)80044-6

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✦ Synopsis

The K-LL spectrum in nitrogen has been measured with a high-resolution electron spectrometer using 1) 3 keV electrons and 2) AIKa X-rays to produce the initial K vacancy. In the high-energy portion of the Auger spectrum, lines at 383.8 eV and 386.7 eV and a band roughly between 368 eV and 380 eV were found as a result of electron bombardment but were missing with the X-ray irradiation. The reason for these differences is ascribed to the ohenomenon of exciting a K electron into an unoccupied _ molecular orbital followed by autoionization.

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