Identification of branched oligosilanes in the phenylsilane dehydrocoupling reaction
✍ Scribed by Jiří Pinkas; Ivana Císařová; Jindřich Karban; Jan Schraml; Jan Sýkora
- Book ID
- 116680352
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 552 KB
- Volume
- 710
- Category
- Article
- ISSN
- 0022-328X
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Direct detection of the products of the 0 + C2H3Br reaction occurring in high-intensity room temperature crossed beams reveals that the reaction proceeds by three reactive channels, the products of which are, 1. CH3 + BrCO (and/ or Br + CO); 2. CH2 Br + HCO (and possibly H + CO), and 3. HzCzO + HBr.
Lower explosion limits in hydrogco-oxygco and deuterium-oxyge/\* mixtures have been measured in the diffusion regime, From the data, rate constants are calculated for 1he reactions H + O~ ~ OH + O and D + O~ ~ OD + O between 800 ' ~ and ! 000~K. Activation energies are found to differ by the differe