Identification of (3Z,6Z)-1,3,6–9,10-epoxyheneicosatriene and (3Z,6Z)-1,3,6–9,10-epoxyeicosatriene in the sex pheromone of hyphantria cunea
✍ Scribed by M. Tóth; H.R. Buser; A. Peña; H. Arn; K. Mori; T. Takeuchi; L.N. Nikolaeva; B.G. Kovalev
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 297 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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Total Synthesis of Enantiomers of (3Z,6Z)-cis-9,10-Epoxy 1,3,6-Henicosatriene -The Pheromonal Component of Diacrisia obliqua. -Key steps in the asymmetric synthesis of the title compounds, e.g. (XIII), are the Sharpless epoxidation, an alkylative epoxide rearrangement and a stereoselective Wittig o