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ChemInform Abstract: Total Synthesis of Enantiomers of (3Z,6Z)-cis-9,10-Epoxy 1,3,6-Henicosatriene — The Pheromonal Component of Diacrisia obliqua.

✍ Scribed by J. S. YADAV; M. Y. VALLI; A. R. PRASAD

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199842247

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✦ Synopsis

Total Synthesis of Enantiomers of (3Z,6Z)-cis-9,10-Epoxy 1,3,6-Henicosatriene -The Pheromonal Component of Diacrisia obliqua.

-Key steps in the asymmetric synthesis of the title compounds, e.g. (XIII), are the Sharpless epoxidation, an alkylative epoxide rearrangement and a stereoselective Wittig olefination (some yields not given or given in g). -(YADAV,

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