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Identification and quantitation of trace amounts of barbiturates with glass capillary gas chromatography

✍ Scribed by Dünges, W. ;Langlais, R. ;Schlenkermann, R.

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
310 KB
Volume
2
Category
Article
ISSN
0935-6304

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✦ Synopsis

Abstract

Pre‐chromatographic reactions are no longer a necessary evil. Equipment such as the microrefluxer now allows reproducible 7‐μl‐reactions to be carried out in a short time. Thus multiple derivatisations can be used together with glass capillary GC for routine identifications. The method has been succesfully applied to barbiturates. Retention data of their methyl‐, allyl‐ and benzyl‐derivatives are given.

Quantitative blood level determinations are briefly discussed.

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