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Identification and fragmentation of hydrolyzed aluminum species by electrospray ionization tandem mass spectrometry

✍ Scribed by Arja Sarpola; Vesa Hietapelto; Jorma Jalonen; Jukka Jokela; Risto S. Laitinen; Jaakko Rämö

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
279 KB
Volume
39
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Earlier characterization of some hydrolysis products of AlCl~3~·6H~2~O was confirmed by electrospray ionization tandem mass spectrometry with increasing collision energy of projectile ions. At lower collision energies, the aqua ligands were stripped off. At higher energies, two hydroxo groups formed a bridging oxo group with loss of one water molecule. Aluminum complexes could also capture aqua ligands in the collision chamber so long as the parent ion did not fragment, and the fragment ion spectra broadened toward higher m/z values. The chloro ligands were eliminated as hydrochloric acid. The aluminum cores remained highly intact. Copyright © 2004 John Wiley & Sons, Ltd.

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