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Identification and Characterization of Conjugated Fatty Acid Methyl Esters of Mixed Double Bond Geometry by Acetonitrile Chemical Ionization Tandem Mass Spectrometry

✍ Scribed by Michaud, Anthony L.; Yurawecz, Martin P.; Delmonte, Pierluigi; Corl, Benjamin A.; Bauman, Dale E.; Brenna, J. Thomas


Book ID
120494070
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
104 KB
Volume
75
Category
Article
ISSN
0003-2700

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Trimethylsilylated methyl esters of octadecadienoic, eicosadienoic, and octadecatrienoic acids, after stereospecific oxidation, were investigated by combined gas chromatography-chemical ionization mass spectrometry. Molecular weight could be determined by the ions at m/e(M -1)' and (M + 73)+ and the