CN B-X emission has been observed upon pulsed laser excitation of the A 'II v= 10 vibrational manifold, which is nearly isoenergetic with B \*Z + v=O. Because of the B-A perturbation, a number of v,= 10 rotational levels have significant B state character. For short observation intervals, the B-X em
ICN photodissociation and predissociation: CN*(A 2Πi) fluorescence excitation spectrum and CN† (X 2Σ+) chemical laser emission
✍ Scribed by Gary A. West; Michael J. Berry
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 549 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
New ICN photochemical experiments [viz., observation of CNt(X *x> chemical laser emission in the presence of rare gas atom collision partners and determination of the CN*<A *IQ) fluorescence excitation spectrum] are reported and are used to clarify the mechanism of ICN photodissociation and predissociation in the 1550-2000 A spectral region.
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