i-PP/HDPE blends. III. Characterization and compatibilization at lower i-PP contents

✍ Scribed by H. P. Blom; J. W. Teh; A. Rudin

• Book ID: 102656263
• Publisher: John Wiley and Sons
• Year: 1996
• Tongue: English
• Weight: 749 KB
• Volume: 61
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19960808)61:6<959::aid-app10>3.0.co;2-q

✦ Synopsis

The mechanical properties of high-density polyethylene (HDPE)-rich i-PPIHDPE blends were studied. Two grades of HDPE were investigated, one with a melt viscosity close to that of the polypropylene (PP) and the other having a much lower melt viscosity. Compatibilization of the 10/90 i-PP/HDPE blend with three copolymers (an ethylene/propylene/ diene [EPDM] copolymer and two ethylene/vinylacetate [EVA] copolymers, differink I their VA content) was also investigated. Blends of PP with the low melt viscosity HDPE displayed poor mechanical properties. It was not possible to improve these properties sufficiently with EPDM or EVA. In the case where viscosity matching was achieved between PP and HDPE, addition of i-PP (up to 30%) to HDPE resulted in a large drop in the impact strength of the blends, compared to that of the neat HDPE. A large drop (>50%) was also observed in the ultimate tensile elongation. However, the flexural modulus, yield stress, and ultimate tensile strength all increased with the introduction of i-PP into HDPE. Modification of these blends with an EPDM resulted in the return of all properties to values very close to those of the neat HDPE. The ultimate tensile elongation of the EPDMmodified i-PP/HDPE blend even exceeded that of the virgin HDPE. It was also found that although EVAs can be used to compatibilize these blends these additives were not as effective as was the EPDM.