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Hypotensive Agents. X. 3-Azabicyclo[3.3.0]octane Derivatives1,2

✍ Scribed by RICE, LEONARD M.; GROGAN, CHARLES H.

Book ID
115545819
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
630 KB
Volume
24
Category
Article
ISSN
0022-3263

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Highly diastereoselective mercury-mediat
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Enantiopure 2-azabicyclo[3.3.0]octanes 1a-d and ent-1e pure compounds (2c,d and ent-2e). The structure of compounds 2a and ent-2e was confirmed by an X-ray study. were oxidized with mCPBA to provide either diastereomeric pairs of N-oxides (2a/3a and 2b/3b) or diastereomerically The factors that affe