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Formation of Chiral N-Oxides from 2-Azabicyclo[3.3.0]octanes

✍ Scribed by Hans Günter Aurich; Michael Soeberdt; Klaus Harms

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
248 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis

Enantiopure 2-azabicyclo[3.3.0]octanes 1a-d and ent-1e pure compounds (2c,d and ent-2e). The structure of compounds 2a and ent-2e was confirmed by an X-ray study. were oxidized with mCPBA to provide either diastereomeric pairs of N-oxides (2a/3a and 2b/3b) or diastereomerically The factors that affect the oxidation process are discussed.

creasing size of the ester group, as is exemplified by the (Z)/

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