𝔖 Bobbio Scriptorium
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Hypophosphite mediated carboncarbon bond formation: A clean approach to radical methodology

✍ Scribed by Stephen R. Graham; John A. Murphy; David Coates

Book ID
104260915
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
128 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Hypophosphorous acid (H3PO2) and its corresponding l-ethylpiperidine salt have been used to mediate carbon-carbon bond forming radical reactions in both aqueous and organic media.The methods used avoid many of the problems associated with tributyltin hydride based methodoh)gy.

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Carboncarbon bond formation via intermolecular carbon radical addition to aldoxime ethers
✍ Hideto Miyabe; Ryouhei Shibata; Chikage Ushiro; Takeaki Naito 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 225 KB

The first example of intermolecular carbon radical addition to unactivated aldoxime ethers in the preseace of BF3.OEt2 has provided a new efficient carbon-carbon bond-forming method for the synthesis of a variety of amines.