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Hypohalogenation of functionally substituted acetylenic norbornenes

✍ Scribed by M. G. Veliev; O. A. Sadygov; M. I. Shatirova; Kh. M. Alimardanov

Book ID
111464789
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
238 KB
Volume
44
Category
Article
ISSN
1070-4280

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## Abstract Photochemical reactions of norbornadiene with substituted acetylenes in the presence of Fe(CO)~5~ gave various products of different types, depending on the nature of the acetylene. The results are summarized in __Table 1__. The cyclopentanone **1** was always formed in these reactions.

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## Abstract The addition of phenyl(trichloromethyl)mercury to five substituted norbornenes is described, and the results compared with those obtained with bicyclo[2.2.2]oct‐2‐ene and 3,3,5,5‐tetramethylcyclopentene. The reaction proves to be useful for synthetic purposes, in that it leads usually t