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Hypervalent iodine induced nucleophilic additions to alkenes: Synthesis of 1,2-diperchlorates

โœ Scribed by Antonella De Mico; Roberto Margarita; Luca Parlanti; Giovanni Piancatelli; Andrea Vescovi


Book ID
104208204
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
243 KB
Volume
53
Category
Article
ISSN
0040-4020

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โœฆ Synopsis


a novel iodine (III) reagent has been developed by the BAIB/Mg(CIO4)2 reagent combination. Reaction of this reagent with alkenes yielded 1,2-diperchlorates.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Hypervalent Iodine
โœ A. DE MICO; R. MARGARITA; L. PARLANTI; G. PIANCATELLI; A. VESCOVI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

Hypervalent Iodine Induced Nucleophilic Additions to Alkenes: Synthesis of 1,2-Diperchlorates. -Bis(perchlorate)iodo benzene, generated in situ from a reagent combination Mg(ClO 4 ) 2 /Ph-J(O-Ac) 2 and stable in a pure form at 25 โ€ข C for weeks, is found to be effective for the conversion of unactiva