This paper presents a study of the spectroscopy of \({ }^{12} \mathrm{CF}_{3}{ }^{79} \mathrm{Br}\) using the Doppler-free saturated absorption technique. Many lines in the \(\nu_{1}\) fundamental and \(\nu_{1}+\nu_{6} \leftarrow \nu_{6}\) hot band of this molecule have been recorded using the \(9-\
Hyperfine Spectroscopy of CF379Br in the Ground, ν1, ν6, and ν1 + ν6 States: A Laser-Radiofrequency Double Resonance Study at High Resolution
✍ Scribed by A.J. Gray; R.J. Butcher
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 833 KB
- Volume
- 161
- Category
- Article
- ISSN
- 0022-2852
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The n {1 4 / 2n 0 6 and n |1 4 / 2n {2 6 perpendicular components and the n {1 4 / 2n {2 6 parallel component of the CH 3 79 Br isotopomer have been found and studied in high resolution ( 0.006 cm 01 ) . Both perpendicular components are linked altogether and also to the n 2 / n 3 / n 4 band by anha
Direct /-type doubling transitions in the 06 = 1 state of CF379Br, CF3SIBr and CF3I have been observed using the technique of Fourier transform microwave spectroscopy in the range 4.5-8 GHz. The transitions covered a range of J values from 38-47 for both isotopomers of CF3Br and from 40-51 for CFaI.