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Hyperconjugation not steric repulsion leads to the staggered structure of ethane

✍ Scribed by Pophristic, Vojislava; Goodman, Lionel


Book ID
109774819
Publisher
Nature Publishing Group
Year
2001
Tongue
English
Weight
219 KB
Volume
411
Category
Article
ISSN
0028-0836

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The Case for Steric Repulsion Causing th
✍ F. Matthias Bickelhaupt; Evert Jan Baerends 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB

It has recently been argued [1,2] that the barrier to rotation around the C À C bond in ethane is not to be explained by the generally accepted picture of steric hindrance between vicinal CÀH bonds in the eclipsed conformation but is caused by more favorable orbital interaction in the staggered conf