𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Case for Steric Repulsion Causing the Staggered Conformation of Ethane

✍ Scribed by F. Matthias Bickelhaupt; Evert Jan Baerends

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
130 KB
Volume
115
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The Case for Steric Repulsion Causing th
The Case for Steric Repulsion Causing the Staggered Conformation of Ethane
✍ F. Matthias Bickelhaupt; Evert Jan Baerends 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB

It has recently been argued [1,2] that the barrier to rotation around the C À C bond in ethane is not to be explained by the generally accepted picture of steric hindrance between vicinal CÀH bonds in the eclipsed conformation but is caused by more favorable orbital interaction in the staggered conf

Contrasting conformational behavior of 5
Contrasting conformational behavior of 5-methylsulfonyl-1,3-dioxane and -1,3-dithiane in the minimization of steric and electrostatic repulsive interactions
✍ J.Samuel Cruz-Sánchez; Eusebio Juaristi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 206 KB

The preparation of novel 1,3-dithiane derivatives, cis-and trans-2-tert-butyl-5-methylsulfonyl-1,3-dithiane, was achieved by acid-catalyzed condensation of 2-methylsulfonyl-1,3-propanedithiol with pivalaldehyde. The former dithiol was obtained from allylmethylsulfide via the Knochel-Normant brominat