Hydroxyselenation of allylic alcohols
β Scribed by Matthew A. Cooper; A.David Ward
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 155 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Dichlorocarbene reacts with secondary allylic alcohols to form largely a single diastereomeric cyclopropane regardless of the olefin substitution pattern at the position beta to the carbinol carbon.
Regioselective allylmetallation of allylic alcohol has been accomplished by treatment with allylzinc in the presence of a nickel catalyst. Benzylic protective group of allyl alcohol facilitates the allylmetallation. During the past two decades many investigations in the field of allylmetallation of
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