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Hydroxynitrile lyase catalysed synthesis of heterocyclic (R)- and (S)-cyanohydrins

✍ Scribed by Manuela Avi; Martin H. Fechter; Karl Gruber; Ferdinand Belaj; Peter Pöchlauer; Herfried Griengl

Book ID
108282736
Publisher
Elsevier Science
Year
2004
Tongue
French
Weight
439 KB
Volume
60
Category
Article
ISSN
0040-4020

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✍ Whittall, John; Sutton, Peter 📂 Article 📅 2009 🏛 John Wiley & Sons, Ltd ⚖ 377 KB 👁 2 views

The hydroxynitrile lyase (HNL)-catalysed cyanohydrin reaction is a useful method to synthesize enantiopure -hydroxy nitriles and the corresponding -hydroxy acids. 1,2 However, small ketones, such as 2-butanone, are converted with low selectivities, due to the poor discrimination between methyl and e