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Hydroxylation of phenol over TS-1: Surface and solvent effects

โœ Scribed by A. Tuel; S. Moussa-Khouzami; Y.Ben Taarit; C. Naccache


Publisher
Elsevier Science
Year
1991
Weight
619 KB
Volume
68
Category
Article
ISSN
0304-5102

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Comparison between TS-1 and TS-2 in the
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The hydroxylation of phenol with hydrogen peroxide has been carried out over a series of titanium silicalites. Results have shown that the activity of the catalyst strongly depended on the synthesis route and on the crystal size. For TS-1 and TS-2 samples with similar titanium contents and crystal a

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Water addition to a reaction solvent accelerates the catalytic oxidation of phenol with hydrogen peroxide over titanosilicalite-1 (TS-1). The amount of produced dihydroxybenzene (hydroquinone and catechol) increases from 4.33 to 6.58 mmol with increasing the water concentration in methanol solvent f