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Hydroxylation of phenol over Sn-silicalite-1 molecular sieve: solvent effects

✍ Scribed by Nawal Kishor Mal; Arumugamangalam V. Ramaswamy


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
1022 KB
Volume
105
Category
Article
ISSN
1381-1169

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Vanadium silicate molecular sieves with MEL structure (VS-2) are found to be active in the hydroxylation of phenol with hydrogen peroxide, a reaction which is commercially practiced over titanium silicalite (TS-1 and TS-2) catalysts. Among various reaction parameters, the influence of the solvent on

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Titanium silicalite-1 samples of different particle size are synthesised and characterised by X-ray diffraction (XRD), photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS), Raman and infrared spectroscopy. Size histograms are taken from transmission electron micrographs. Temporal