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Hydroxylation of benzylic and allylic sites by plant cultured suspension cells

✍ Scribed by Hiroki Hamada; Toshinori Tanaka; Tsutomu Furuya; Hiroki Takahata; Hideo Nemoto

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 62 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)02132-8

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✦ Synopsis

A novel transformation of a-substituted benzylcyanides by hydroxylation of benzyl sites using cultured cells of cotton, Gossypium hirsutum, producing alkano-or benzophenones via presumably a-cyanohydrin is demonstrated. Also regioselective hydroxylation of 4S-(-)-perillyl alcohol and 3S-(-)-citronellol by cultured suspension cells of Catharanthus roseus is reported.

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