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Hydroxylation of benzene in the system vanadium(V)-hydrogen peroxide-acetic acid

✍ Scribed by N. I. Rudakova; M. V. Klyuev; Yu. G. Erykalov; D. N. Ramazanov

Book ID
111459008
Publisher
Springer
Year
2006
Tongue
English
Weight
32 KB
Volume
76
Category
Article
ISSN
1070-3632

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Oxidations by the system β€œhydrogen peroxide - manganese(IV) complex - acetic acid” β€” Part II. Hydroperoxidation and hydroxylation of alkanes in acetonitrile
✍ Georgiy B Shul'pin; Georg SΓΌss-Fink; John R Lindsay Smith πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 Β°C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac