✦ LIBER ✦

Catalytic oxidation of benzoic acid in acetic acid: Aromatic hydroxylation with in situ-generated hydrogen peroxide

✍ Scribed by Akikazu Itoh; Yasushi Kuroda; Tomoyuki Kitano; Guo Zhi-Hu; Atsutaka Kunai; Kazuo Sasaki

Publisher: Elsevier Science
Year: 1991
Weight: 532 KB
Volume: 69
Category: Article
ISSN: 0304-5102
DOI: 10.1016/0304-5102(91)80146-t

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Fast Oxidation of Organic Sulfides by Hy

Fast Oxidation of Organic Sulfides by Hydrogen Peroxide by In Situ Generated Peroxynitrous Acid

✍ Stéphane Vayssié; Horst Elias 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 3 views

Catalytic hydroxylation of benzene and c

Catalytic hydroxylation of benzene and cyclohexane using in situ generated hydrogen peroxide: new mechanistic insights and comparison with hydrogen peroxide added directly

✍ Joseph E. Remias; Thomas A. Pavlosky; Ayusman Sen 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 205 KB

In situ Formation of Peracetic Acid in I

In situ Formation of Peracetic Acid in Iron-Catalyzed Epoxidations by Hydrogen Peroxide in the Presence of Acetic Acid

✍ Megumi Fujita; Lawrence Que Jr. 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 2 views

## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=tris‐(2‐pyridylmethyl)amine; bpmen=__N,N′__‐bis‐(2‐pyridylmethyl)‐__N,N′‐__dimethyl‐1,2‐ethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.

Oxidations by the system “hydrogen perox

Oxidations by the system “hydrogen peroxide - manganese(IV) complex - acetic acid” — Part II. Hydroperoxidation and hydroxylation of alkanes in acetonitrile

✍ Georgiy B Shul'pin; Georg Süss-Fink; John R Lindsay Smith 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 °C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac

In Situ Generation of Nitroso Compounds

In Situ Generation of Nitroso Compounds from Catalytic Hydrogen Peroxide Oxidation of Primary Aromatic Amines and Their One-Pot Use in Hetero-Diels–Alder Reactions

✍ Dongbo Zhao; Mikael Johansson; Jan-E. Bäckvall 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB

Square-Wave Voltammetric Determination o

Square-Wave Voltammetric Determination of Hydrogen Peroxide Generated from the Oxidation of Ascorbic Acid in a Model Wine Base

✍ Mark P. Bradshaw; Paul D. Prenzler; Geoffrey R. Scollary 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 2 views

The stoichiometry of the formation of hydrogen peroxide from ascorbic acid in a model wine system has been examined by square-wave voltammetry (SWV) on a hanging mercury drop electrode. Both ascorbic acid and hydrogen peroxide could be determined in the same test sample by first employing an anodic