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Hydroxo and Oxo Complexes of Platinum(II) Stabilized by Phosphanes: Synthesis and Characterization − X-ray Structures of cis-[L2Pt(μ-OH)]2(NO3)2 (L = PMe2Ph, PMePh2) and [{cis-(PMe2Ph)2Pt}3(μ-O)2]Cl2

✍ Scribed by Bruno Longato; Giuliano Bandoli; Alessandro Dolmella


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
177 KB
Volume
2004
Category
Article
ISSN
1434-1948

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo