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Hydroxide-ion initiated reactions under phase-transfer catalysis conditions. 6. Dehydrobromination of (2-bromoethyl)benzene via slow hydroxide-ion extraction

✍ Scribed by Halpern, Marc; Sasson, Yoel; Rabinovitz, Mordecai


Book ID
127218820
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
291 KB
Volume
49
Category
Article
ISSN
0022-3263

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Hydroxide-ion-initiated reactions under
✍ Halpern, Marc; Zahalka, Hayder A.; Sasson, Yoel; Rabinovitz, Mordecai πŸ“‚ Article πŸ“… 1985 πŸ› American Chemical Society 🌐 English βš– 648 KB

In addition, 14 (7 mg, 8%) was obtained. 4-tert-Butyl-l-hydroperoxy-9-oxabicyclo[4.2.l]nonanes (16 and 17). A solution of 14 (92 mg, 0.50 mmol) was rearrnged in THF (2 mL) and 90% H20z (2 mL, 72 mmol HzOz) containing TsOH.H,O (120 mg, 0.60 mmol) for 48 h according to procedure F. Preparative TLC of