A mixed-valent Fe(II/III) phosphate, NaFe 3.67 (PO 4 ) 3 , has been synthesized by high-temperature/high-pressure hydrothermal methods and characterized by single-crystal X-ray diffraction, EDAX, magnetic susceptibility, Mo] ssbauer, infrared, and diffuse reflectance spectroscopies, DTA, and bond va
Hydrothermal synthesis, structure and characterization of new NASICON related potassium iron (III) pyrophosphate
β Scribed by G. S. Gopalakrishna; B. H. Doreswamy; M. J. Mahesh; M. Mahendra; M. A. Sridhar; J. Shashidhara Prasad; K. G. Ashamanjari
- Book ID
- 110646916
- Publisher
- Springer-Verlag
- Year
- 2005
- Tongue
- English
- Weight
- 501 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0250-4707
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## Synthesis and Characterization of New -The title hydrate is synthesized by reaction of KNO 2 with SbF 3 (molar ratio 0.5:1 to 5:1) in water at room temperature. The new compound crystallizes in the rhombic system and appears to be isostructural to NaM 2 SbF 5 -type compounds. Spectral and therm