Hydrothermal Synthesis and Structural Characterization of (VO)2(PO4)2H2PO4.cntdot. N2C2H10, a New Three-Dimensional, Organically Templated Mixed-Valence Vanadium Phosphate Related to the 2VOSO4.cntdot.H2SO4 Structure
β Scribed by Harrison, William T. A.; Hsu, Ken; Jacobson, Allan J.
- Book ID
- 127066203
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 315 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0897-4756
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Two new phases, (C 4 H 12 N 2 )(H 3 O)[(VOPO 4 ) 4 (H 2 O)H 2 PO 4 ] ' 3H 2 O (1) and (C 4 H 12 N 2 )[(VO)(VO 2 ) 2 (H 2 O)(PO 4 ) 2 ] (2) have been synthesized hydrothermally and characterized by single crystal X-ray di4raction, thermogravimetric analysis, and magnetic susceptibility. Compound 1 ha
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Two new organo-templated three-dimensional 6uorinated titanium phosphates Ti 4 (HPO 4 ) 2 (PO 4 ) 4 F 2 ' C 4 N 2 H 12 ' H 2 O 1 and Ti 4 (HPO 4 ) 2 (PO 4 ) 4 F 2 ' C 2 N 2 H 10 ' H 2 O 2 have been prepared hydrothermally in the presence of piperazine (C 4 N 2 H 10 ) and ethylenediamine (C 2 N 2 H 8