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Hydrothermal synthesis and crystal structure of a novel layered vanadate complex containing double helical chains: [{Zn(2,2′-bpy)}2V8O21](2,2′-bpy=2,2′-bipyridine)

✍ Scribed by Dongrong Xiao; Yu Hou; Enbo Wang; Yangguang Li; Jian Lü; Lin Xu; Changwen Hu

Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
392 KB
Volume
691
Category
Article
ISSN
0022-2860

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✦ Synopsis

A novel organic -inorganic hybrid vanadate complex [{Zn(2,2 0 -bpy)} 2 V 8 O 21 ] 1 (2,2 0 -bpy ¼ 2,2 0 -bipyridine) was synthesized by the hydrothermal reaction of V 2 O 5 , ZnCl 2 , 2,2 0 -bpy and water. Its structure was determined by elemental analyses, XPS spectra, TG analysis, IR spectrum and the single-crystal X-ray diffraction.

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An organic+inorganic hybrid solid, (Cu(2,2-bpy) 2 ) 2 Mo 8 O 26 , has been hydrothermally synthesized and structurally characterized by single-crystal X-ray di4raction. Dark green crystals crystallize in the orthorhombic system, space group Pna21, a ‫؍‬ 24.164(5), b ‫؍‬ 18.281(4), c ‫؍‬ 11.877(2) A