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Hydrothermal synthesis and crystal structure of a mixed-valence Cu(I)/Cu(II) complex: [Cu4(ophen)4(mtp)] (Hophen=2-hydroxy-1,10′-phenanthroline, mtp=2-methyl-terephthalate acid)

✍ Scribed by Yuhua Feng; Zhangang Han; Jun Peng; Xiangrong Hao


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
310 KB
Volume
734
Category
Article
ISSN
0022-2860

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,