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Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction

โœ Scribed by Talley, Catherine E.; Bean, Amanda C.; Albrecht-Schmitt, Thomas E.

Book ID
120627612
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
31 KB
Volume
39
Category
Article
ISSN
0020-1669

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Hydrothermal Syntheses, Structures, and
Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids
โœ Philip M. Almond; Catherine E. Talley; Amanda C. Bean; Shane M. Peper; Thomas E. ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 212 KB

Three new one-dimensional uranium oxy6uorides, (C 5 H 14 N 2 ) U 2 O 4 F 6 (AU1-3), (C 5 H 6 N)UO 2 F 3 (AU1-4), and (C 3 H 5 N 2 ) UO 2 F 3 (AU1-5), have been prepared from the reactions of UO 3 with HF and homopiperazine (C 5 H 12 N 2 ), pyridine, or pyrazole at 1803C in aqueous media. In all case